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研究室紹介 構造化学研究室

教員鈴木光明(助教) 博士(理学)
略歴 2008年 城西大学理学部化学科卒業
2010年 城西大学理学研究科物質科学専攻(修士課程)修了
2013年 筑波大学大学院数理物質科学研究科化学専攻博士後期課程 修了(博士(理学)取得)
2013年 公益財団法人国際科学振興財団研究員
2014年 東京学芸大学博士研究員
2015-2016年 東京学芸大学特任講師
2016年 城西大学理学部化学科助教
担当科目 (学部) 化学基礎セミナー(前)、合成化学特論(前)、無機分析化学実験(後)、化学ゼミナール(通年)、卒業研究
専門分野構造有機化学、フラーレン化学、有機結晶
所属学会日本化学会
基礎有機化学会
フラーレン・ナノチューブ・グラフェン学会
居室 1-314
院生 0名
4年生 5名
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研究内容

近年注目されているナノカーボンを代表するフラーレンは、炭素第三の同素体であり、新規な分子構造に由来する種々の特徴ある物理的化学的特性を示すかご状炭素素材として魅力ある物質群です。「フラーレン球面の外側および内側の化学」に注目し、新規金属内包フラーレンの合成、機能化フラーレンの合成、フラーレンを配位子とする錯体の合成など、新規フラーレン化合物の合成を目指し、それらの構造と物性について研究しています。

昨年度の卒業研究題目

研究業績(学術論文)

  1. “D2d(23)-C84 versus Sc2C2@D2d(23)-C84: Impact of Endohedral Sc2C2 Doping on Chemical Reactivity in the Photolysis of Diazirine”
    Michio Yamada, Yukiko Tanabe, Jing-Shuang Dang, Satoru Sato, Naomi Mizorogi, Makoto Hachiya, Mitsuaki Suzuki, Tsuneyuki Abe,
    Hiroki Kurihara, Yutaka Maeda, Xiang Zhao, Yongfu Lian, Shigeru Nagase, Takeshi Akasaka,
    Journal of the American Chemical Society 2016, 138, 16523-16532
  2. “The Unanticipated Dimerization of Ce@C2v(9)-C82 upon Co-crystallization with Ni(octaethylporphyrin) and Comparison with Monomeric   M@C2v(9)-C82 (M = La, Sc, and Y)”
    Mitsuaki Suzuki, Michio Yamada, Yutaka Maeda, Satoru Sato, Yuta Takano, Filip Uhlik, Zdenek Slanina, Yongfu Lian, Xing Lu, Shigeru Nagase, Marilyn M. Olmstead, Alan L. Balch, and Takeshi Akasaka,
    Chemstry - A Euroean Journal2016, 22, 18115-18122.
  3. “Synthesis and Photoinduced Electron-Transfer Reactions in a La2@Ih-C80–Phenoxazine Conjugate”
    Takeshi Akasaka, Akira Nakata, Marc Rudolf, Wei-Wei Wang, Michio Yamada, Mitsuaki Suzuki, Yutaka Maeda, Ryo Aoyama, Takahiro Tsuchiya, Shigeru Nagase, Dirk M. Guldi,
    ChemPlusChem, 2016, 10.1002/cplu.201600391. 
  4. “Thermal Stability of Oxidized Single-Walled Carbon Nanotubes: Competitive Elimination and Decomposition Reaction Depending on the Degree of Functionalization”,
    Yutaka Maeda, Erika Sone, Akane Nishino, Yuri Amagai, Wei-Wei Wang, Michio Yamada, Mitsuaki Suzuki, Jun Matsui, Masaya, Mitsuishi, Toshiya Okazaki, Shigeru Nagase,
    Chemstry - A Euroean Journal 2016, 22, 15373-15379.
  5. “Tuning of the photoluminescence and up- conversion photoluminescence properties of single-walled carbon nanotubes by chemical functionalization”
    Yutak Maeda, Shun Minami, Yuya Takehana, Jing-Shuang Dang, Shun Aota, Kazunari Matsuda, Yuhei Miyauchi, Michio Yamada,
    Mitsuaki Suzuki, Rui-Sheng Zhao, Xiang Zhao and Shigeru Nagase
    Nanoscale 2016, 8, 16916-16921.
  6. “Molecular Location Sensing Approach by Anisotropic Magnetism of an Endohedral Metallofullerene”,
    Yuta Takano, Ryo Tashita, Mitsuaki Suzuki, Shigeru Ngase, Hiroshi Imahori, Takeshi Akasaka,
    Journal of the American Chemical Society 2016, 138, 8000–8006.
  7. "Effective derivatization and extraction of insoluble missing lanthanum metallofullerenes La@C2n (n = 36–38) with iodobenzene",
    Yutaka Maeda, Takayoshi Tsuchiya, Takashi Kikuchi, Hidefumi Nikawa, Tao Yang, Xiang Zhao, Zdenek Slanina, Mitsuaki Suzuki,
    Michio Yamada, Yongfu Lian, Shigeru Nagase, Xing Lu, Takeshi Akasaka,
    Carbon2016, 98, 67–73.
  8. "Preparation, Structural Determination, and Characterization of Electronic Properties of Bis-silylated and Bis-germylated Lu3N@Ih-C80",
    Masahiro Kako, Kyousuke Miyabe, Kumiko Sato, Mitsuaki Suzuki, Naomi Mizorogi, Wei-Wei Wang, Michio Yamada, Yutaka Maeda,
    Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Takeshi Akasaka,
    Chemstry - A Euroean Journal 2015, 21, 16411–16420.
  9. "Control of the photoluminescence properties of single-walled carbon nanotubes by alkylation and subsequent thermal treatment",
    Yutaka Maeda, Yuya Takehana, Michio Yamada, Mitsuaki Suzuki, Tatsuya Murakami,
    Chemical Communications 2015, 51, 13462–13465.
  10. "La2@C72 open cage Regioselective Cage Opening of La2@D2(10611)-C72 with 5,6-Diphenyl-3-(2-pyridyl)- 1,2,4-triazine",
    Michio Yamada, Yasuhiro Muto, Hiroki Kurihara, Zdenek Slanina, Mitsuaki Suzuki, Yutaka Maeda, Yves Rubin, Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Xing Lu, Takeshi Akasaka,
    Angewandte Chemie International Edition 2015, 54, 2232–2235.
  11. "Hiding and Recovering Electrons in a Dimetallic Endohedral Fullerene: Air-Stable Products from Radical Additions",
    Michio Yamada, Hiroki Kurihara, Mitsuaki Suzuki, Masayoshi Saito, Zdenek Slanina, Filip Uhlík, Toshihiro Aizawa, Tatsuhisa Kato,
    Marilyn M. Olmstead, Alan L. Balch, Yutaka Maeda, Shigeru Nagase, Xing Lu, Takeshi Akasaka,
    Journal of the American Chemical Society 2015, 137, 232–238.
  12. "Polymorphs Related by an Enantiotropic Phase Transition but Having Only Order-Disorder-Level Conformational Differences in a Spiro-Conjugated Imidasolidine Ring Compound",
    Mitsuaki Suzuki, Yutaka Maeda, Motoko Akita, Hiroyuki Teramae, Keiji Kobayashi,
    Crystal Growth & Design 2014, 14, 6302–6310.
  13. "Isolation and characterization of [5,6]-pyrrolidino- Sc3N@Ih-C80 diastereomers",
    Yutaka Maeda, Masato Kimura, Chihiro Ueda, Michio Yamada, Toru Kikuchi, Mitsuaki Suzuki, Wei-Wei Wang, Naomi Mizorogi, Nikolaos Karousis, Nikos Tagmatarchis, Tadashi Hasegawa, Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Takeshi Akasaka,
    Chemical Communications 2014, 50, 12552–12555.
  14. "Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes",
    Qin Zhou, Hui Li, Yongfu Lian, Mitsuaki Suzuki, Lipiao Bao, Wenting Cai, Wei-Wei Wang, Shigeru Nagase, Xing Lu, Takeshi Akasaka,
    Chemical Communications 2014, 50, 9876–9878.
  15. "Regioselective Benzyl Radical Addition to an Open-Shell Cluster Metallofullerene. Crystallographic Studies of Cocrystallized Sc3C2@Ih-C80
    and Its Singly Bonded Derivative",
    Hongyun Fang, Hailin Cong, Mitsuaki Suzuki, Lipiao Bao, Bing Yu, Yunpeng Xie, Naomi Mizorogi, Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Takeshi Akasaka, Xing Lu,
    Journal of the American Chemical Society2014, 136, 10534–10540.
  16. "Sc2@C66 Revisited: An Endohedral Fullerene with Scandium Ions Nestled within Two Unsaturated Linear Triquinanes",
    Michio Yamada, Hiroki Kurihara, Mitsuaki Suzuki, Jing Dong Guo, Markus Waelchli, Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Yutaka Maeda, Tadashi Hasegawa, Xing Lu, Takeshi Akasaka,
    Journal of the American Chemical Society 2014, 136, 7611–7614.
  17. "Regioselective Electrosynthesis of Rare 1,2,3,16-Functionalized [60]Fullerene Derivatives",
    Yang Xiao, San-E Zhu, Ding-Jia Liu, Mitsuaki Suzuki, Xing Lu, Guan-Wu Wang,
    Angewandte Chemie International Edition2014, 53, 3006–3010.
  18. "Towards Relative Populations of Non-Isomeric Metallofullerenes, La@C76(Td) vs. La2@C76(Cs,17490)",
    Zdenek Slanina, Filip Uhlík, Shyi-Long Lee, Bo-Cheng Wang, Ludwik Adamowicz, Mitsuaki Suzuki, Masayuki Haranaka, Lai Feng, Xing Lu, Shigeru Nagase, Takeshi Akasaka,
    Fullerenes, Nanotubes, and Carbon Nanostructures2014, 22, 299–306.
  19. "Calculated Temperature Development of the Relative Stabilities of Yb@C82 Isomers",
    Zdenek Slanina, Filip Uhlík, Shyi-Long Lee, Mitsuaki Suzuki, Xing Lu, Naomi Mizorogi, Shigeru Nagase, Takeshi Akasaka,
    Fullerenes, Nanotubes, and Carbon Nanostructures2014, 22, 116–123.
  20. "La2@Cs(17490)-C76: A New Non-IPR Dimetallic Metallofullerene Featuring Unexpectedly Weak Metal–Pentalene Interactions",
    Mitsuaki Suzuki, Naomi Mizorogi, Tao Yang, Filip Uhlík, Zdenek Slanina, Xiang Zhao, Michio Yamada, Yutaka Maeda, Tadashi Hasegawa, Shigeru Nagase, Xing Lu, Takeshi Akasaka,
    Chemstry - A Euroean Journal2013, 19, 17125–17130.
  21. "Molecular Structure and Chemical Property of a Divalent Metallofullerene Yb@C2(13)-C84",
    Wenjun Zhang, Mitsuaki Suzuki, Yunpeng Xie, Lipiao Bao, Wenting Cai, Zdenek Slanina, Shigeru Nagase, Ming Xu,
    Takeshi Akasaka, Xing Lu,
    Journal of the American Chemical Society2013, 135, 12730–12735.
  22. "Highly Regioselective Addition of Adamantylidene Carbene to Yb@C2v(3)-C80 to Afford the First Derivative of Divalent Metallofullerenes",
    Yunpeng Xie, Mitsuaki Suzuki, Wenting Cai, Naomi Mizorogi, Shigeru Nagase, Takeshi Akasaka, Xing Lu,
    Angewandte Chemie International Edition 2013, 52, 5142–5145.
  23. "An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82",
    Shangfeng Yang, Chuanbao Chen, Fupin Liu, Yunpeng Xie, Fengyu Li, Mingzhi Jiao, Mitsuaki Suzuki, Tao Wei, Song Wang, Zhongfang Chen, Xing Lu, Takeshi Akasaka,
    Scientific Reports 2013, 3, 1487.
  24. "Mapping the Metal Positions inside Spherical C80 Cages: Crystallographic and Theoretical studies of Ce2@D5h-C80 and Ce2@Ih-C80",
    Lai Feng, Mitsuaki Suzuki, Naomi Mizorogi, Xing Lu, Michio Yamada, Takeshi Akasaka, Shigeru Nagase,
    Chemistry - A European Journal 2013, 19, 988–993.
  25. "Single-Crystal X-ray Diffraction Study of Three Yb@C82 Isomers Cocrystallized with NiII(octaethylporphrin)",
    Mitsuaki Suzuki, Zdenek Slanina, Naomi Mizorogi, Xing Lu, Shigeru Nagase, Marilyn M. Olmstead, Alan L. Balch, Takeshi Akasaka,
    Journal of the American Chemical Society 2012, 134, 18772–18778.
  26. "Synthesis of a Silylene-Bridged Endohedral Metallofullerene Lu3N@Ih-C80",
    Kumiko Sato, Masahiro Kako, Mitsuaki Suzuki, Naomi Mizorogi, Takahiro Tsuchiya, Marilyn M. Olmstead, Alan L. Balch, Takeshi Akasaka, Shigeru Nagase,
    Chemical Society2012, 134, 16033–16039.
  27. "Tunable Charge-transport Property of Ih-C80 Endohedral Metallofullerenes: Investigation of La2@C80, Sc3N@C80, and Sc3C2@C80",
    Satoru Sato, Shu Seki, Guangfu Luo, Mitsuaki Suzuki, Jing Lu, Shigeru Nagase, Takeshi Akasaka,
    Journal of the American Chemical Society2012, 134, 11681–11686.
  28. "Where Does the Metal Cation Stay in Gd@C2v(9)-C82? A Single-Crystal X-ray Diffraction Study",
    Mitsuaki Suzuki, Xing Lu, Satoru, Sato, Hidefumi Nikawa, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya,
    Shigeru Nagase, Takeshi Akasaka,
    Inorganic Chemistry2012, 51, 5270–5273.
  29. "Polymorphism in Solvate Crystals of Indantrione 1,2-Dioxime",
    Mitsuaki Suzuki, Keiji Kobayashi,
    Crystal Growth & Design 2011, 11, 1814–1820.
  30. "Imino–enamine tautomerism and dynamic prototropy in 1-imino-3-amino-1H-indens",
    Yoko Mukano, Mai Momochi, Yuriko Takanashi, Mitsuaki Suzuki, Hidetsugu Wakabayashi, Hiroyuki Teramae, Keiji Kobayashi,
    Tetrahedron 2010, 66, 605–611.
  31. "Solid-state Transformation of Achiral Crystals to a Chiral Crystal by Guest Release from Host–Guest Inclusion Crystals of Achiral Host Compound",
    Hironori Saito, Mitsuaki Suzuki, Hiroshi Miyamae, Naoto Hayashi, Keiji Kobayashi,
    Chemistry Letters2009, 38, 1080–1081.

研究業績(総説等)

  1. "金属内包フラーレンの構造決定",
    鈴木光明, 山田道夫, 前田優, 永瀬茂, 赤阪健,
    日本結晶学会誌, 2016, 58, 73-78.
  2. "金属カーバイドを内包したフラーレンの化学",
    前田優, 鈴木光明, 永瀬茂, 赤阪健,
    OrganoMetallic NEWS, 2014, 37–41.
  3. "単層カーボンナノチューブとアミンの相互作用"
    前田優, 山田道夫, 鈴木光明,
    導電性フィラー, 導電助剤の分散性向上, 評価, 応用, 第5章 第6節, 261-268.

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